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DC Field | Value | Language |
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dc.contributor.advisor | Hoodless, I. M. | |
dc.contributor.author | Ghosh, Chanchal Kumar | |
dc.date.accessioned | 2017-06-06T13:40:22Z | |
dc.date.available | 2017-06-06T13:40:22Z | |
dc.date.created | 1982 | |
dc.date.issued | 1982 | |
dc.identifier.uri | http://knowledgecommons.lakeheadu.ca/handle/2453/2339 | |
dc.description.abstract | The catalytic decomposition of 2-propanol has been investigated by a micropulse reactor technique in the temperature range from 461 to 547 K on nickel oxide and alumina doped nickel oxide. Nickel oxide is active for the dehydrogenation of 2-propanol, yielding acetone, but the introduction of A1[superscript 3+] ions leads to the development of some dehydration activity; nickel alumlnate is purely a dehydrating catalyst. X-ray diffraction data indicate the formation of the nickel aluminate at the higher dopant concentrations. The variations in catalyst activity and selectivity as a function of catalyst compositions have been roughly divided into three regions: region I, in which there is a significant change in activity and selectivity with very small concentrations of Al[superscript 3+] ions; region II, in which the activity and selectivity remains virtually constant with changes in composition; region III, in which there is a marked increase in activity and dehydration selectivity with Increasing concentrations of Al[superscript 3+] ions The behavior in region I is believed to be associated with electronic changes in nickel oxide brought about by the substitutional incorporation of Al[superscript 3+] ion, while the behaviour in region III is ascribed to increasing amounts of nickel aluminate in the surface zones of the samples. Self-poisoning in the dehydrogenation reaction has been observed and an equation accounting for the self-poisoning kinetics has been proposed. It is suggested that in the dehydrogenation reaction each alcohol molecule uses one active site on the catalyst, while self-poisoning causes elimination of three sites per deactivating event. Strong chemisorption of acetone on the surface is considered to be responsible for the self-poisonlng of the dehydrogenation reaction. The conclusions are supported by conductivity studies of the catalysts under reaction conditions. A characteristic feature of the dehydration reaction is the deviation from linearity in the Arrhenius plots at higher reaction temperatures. Isotope effect measurements show that this is not due to a diffusion controlled reaction. The deviation is believed to be associated with the decomposition of hydroxyl groups on the catalyst surface and investigations of the thermal dehydroxylation of mixed nickel-aluminium hydroxides support this proposal. | |
dc.language.iso | en_US | |
dc.subject | Decomposition (Chemistry) | |
dc.subject | Alcohols | |
dc.subject | Metallic oxides | |
dc.title | Studies on the decomposition of alcohols on metal oxide catalysts | |
dc.type | Thesis | |
etd.degree.name | Master of Science | |
etd.degree.level | Master | |
etd.degree.discipline | Chemistry | |
etd.degree.grantor | Lakehead University | |
Appears in Collections: | Retrospective theses |
Files in This Item:
File | Description | Size | Format | |
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GhoshC1982m-1b.pdf | 15.59 MB | Adobe PDF | View/Open |
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