Please use this identifier to cite or link to this item:
https://knowledgecommons.lakeheadu.ca/handle/2453/2380
Title: | Reactions of Co(II) with sodium cyanotrihydroborate in the presence of a series of bidentate and some monodentate phosphines |
Authors: | Khan, Saeed Iftikhar |
Keywords: | Cobalt Isotopes;Sodium cyanotrihydroborate;Phosphenes |
Issue Date: | 1981 |
Abstract: | The reactions between Co(C10[subscript4])[subscript2].6H[subscript2]O or CoCl[subscript2].6H[subscript2]O, NaBH[subscript3]CN and some monodentate (PPh[subscript3] and Pcy[subscript3]) and a series of bidentate phosphines of the type Ph[subscript2]P-(CH[subscript2])[subscriptn]-PPh[subscript2] (n = 1-4) and also cis and trans Ph[subscript2]P-(CH[subscript2])[subscriptn]-PPh[subscript2] have been studied under a very wide range of experimental conditions. The reactions are affected by (1) the amount of NaBH[subscript3]CN used, (2) the rate of addition of NaBH[subscript3]CN, (3) the temperature, (4) the solvent used and (5) the reaction time. A number of cyanotrihydroborato and other complexes have been produced and others observed but not yet isolated. |
URI: | http://knowledgecommons.lakeheadu.ca/handle/2453/2380 |
metadata.etd.degree.discipline: | Chemistry |
metadata.etd.degree.name: | Master of Science |
metadata.etd.degree.level: | Master |
metadata.dc.contributor.advisor: | Holah, D. G. Hughes, A. N. |
Appears in Collections: | Retrospective theses |
Files in This Item:
File | Description | Size | Format | |
---|---|---|---|---|
KhanS1981m-1b.pdf | 15.46 MB | Adobe PDF | View/Open |
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.