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https://knowledgecommons.lakeheadu.ca/handle/2453/297
Full metadata record
DC Field | Value | Language |
---|---|---|
dc.contributor.advisor | Spivak, Gregory | - |
dc.contributor.author | Beach, Michael T. | - |
dc.date.accessioned | 2012-11-11T03:21:22Z | - |
dc.date.available | 2012-11-11T03:21:22Z | - |
dc.date.created | 2011-12 | - |
dc.date.issued | 2012-11-10 | - |
dc.identifier.uri | http://knowledgecommons.lakeheadu.ca/handle/2453/297 | - |
dc.description.abstract | Conventional phosphine ligands (i.e., those typically bearing alkyl and/or aryl substituents) have played a crucial role in the development of transition metal coordination chemistry. Many structural and electronic variants have been explored, including the class of bis(N-pyrrolidinyl)alkylphosphines. These phosphines generally possess moderate steric properties, yet exhibit exceptional electron-donating properties. The greater Lewis basicity of bis(N-pyrrolidinyl)alkylphosphines likely can be attributed to the additional electron density provided by the lone pair of the planar nitrogen atoms through a dative interaction with the phosphorus donor atom. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | Ruthenium piano-stool complexes | en_US |
dc.subject | Phosphine ligands | en_US |
dc.title | Ruthenium piano stool complexes incorporating novel bis(pyrrolidinyl)alkylphosphines | en_US |
dc.type | Thesis | en_US |
etd.degree.name | M.Sc. | en_US |
etd.degree.level | Master | en_US |
etd.degree.discipline | Chemistry | en_US |
etd.degree.grantor | Lakehead University | en_US |
Appears in Collections: | Electronic Theses and Dissertations from 2009 |
Files in This Item:
File | Description | Size | Format | |
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BeachMT2011m-1a.pdf | PDF/A - 1a compliance | 1.93 MB | Adobe PDF | View/Open |
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