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DC Field | Value | Language |
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dc.contributor.advisor | Gottardo, Christine | - |
dc.contributor.author | Boissy, Christine | - |
dc.date | 2017 | - |
dc.date.accessioned | 2018-02-22T18:21:31Z | - |
dc.date.available | 2018-02-22T18:21:31Z | - |
dc.date.issued | 2017 | - |
dc.identifier.uri | https://knowledgecommons.lakeheadu.ca/handle/2453/4101 | - |
dc.description.abstract | A variety of room temperature ionic liquids have been synthesized and applied to various reactions. Four of these ionic liquids were prepared in a chiral manner: [1-butyl-3- methylimidazolium][L-lactate], [1-butyl-3-methylimidazolium][D-lactate], [1-butyl-3- methylimidazolium][(1S)(+)-10-camphorsulfonate], and [1-butyl-3-methylimidazolium][(1R)(-)-10- camphorsulfonate]. These chiral ionic liquids were used as solvents in asymmetric spiroacetal cyclizations and Truce-Smiles rearrangements to induce chirality to the reactions. Additionally, four other ionic liquids were synthesized for use in electrochemical experiments: [1-butyl-3-methylimidazolium][BF4], [1-butyl-3-methylimidazolium][PF6], [1-butyl-3- methylimidazolium][SCN] and [1-butyl-3-methylimidazolium][Tau]. These ionic liquids were used as an additive during electrochemical nickel deposition and dissolution to improve the effect of the Watts solution. | en_US |
dc.language.iso | en_US | en_US |
dc.subject | Synthetic applications of RTILs | en_US |
dc.subject | Asymmetric synthesis | en_US |
dc.subject | Asymmetric spiroacetal cyclization | en_US |
dc.subject | Truce-smiles rearrangement | en_US |
dc.subject | Electrodeposition/dissolution of nickel in RTIL | en_US |
dc.title | Synthesis and applications of room temperature ionic liquids | en_US |
dc.type | Thesis | - |
etd.degree.name | Master of Science | en_US |
etd.degree.level | Master | en_US |
etd.degree.discipline | Chemistry | en_US |
etd.degree.grantor | Lakehead University | en_US |
Appears in Collections: | Electronic Theses and Dissertations from 2009 |
Files in This Item:
File | Description | Size | Format | |
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BoissyC2017m-1b.pdf | 2.27 MB | Adobe PDF | ![]() View/Open |
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