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Bidentate phosphine complexes of copper (I) : their syntheses and interactions with sodium tetrahydroborate and sodium cyanotrihydroborate
(1981)Copper(l) chloride and perchlorate complexes of the types (L~L)CuCl, (L-L)[subscript 3]Cu[subscript2]X[subscript2] (X=Cl-,C10-4), C(L-L)[subscript2]Cu]C10[subscript4] (L-L=DPPM, DPPE, trans VPP, cis VPP, DPPP, DPPB,DPPPe,DPPH) ... -
Reactions of Co(II) with sodium cyanotrihydroborate in the presence of a series of bidentate and some monodentate phosphines
(1981)The reactions between Co(C10[subscript4])[subscript2].6H[subscript2]O or CoCl[subscript2].6H[subscript2]O, NaBH[subscript3]CN and some monodentate (PPh[subscript3] and Pcy[subscript3]) and a series of bidentate phosphines ... -
Reactions of Ni (II) with sodium cyanotrihydroborate in presence of some bidentate phosphines
(1982)Cyanotrihydroborate-transiton metal ion chemistry has been reviewed. -
Reactions of Ni(II) with NaBh4 and NaBh3 CN in the presence of mono-and bidentate phosphines under CO atmosphere
(1988)Phosphine-substituted carbonyl complexes of Ni have been prepared. The reaction between NiC12.6H20, NaBH4 or NaBH3CN and either PPh3 or a series of phosphines of the type Ph2P-(CH2)n-PPh2 (n=1-5) and also cis-dppe under ... -
Reactions of sodium tetrahydroborate with metal ions in the presence of nitrogen donor ligands
(1977, c197)The work described in this thesis is part of an ongoing effort in these laboratories to determine in more detail how a variety of factors, particularly the nature of added ligands, affects the type of products and the ... -
Simple route to new palladium-carbonyl-bis(diphenylphosphino)methane complexes
The method of synthesizing metal-carbonyl-dppm complexes [dppm = bis(diphenylphosphino)methane) devised by Holah and Hughes has been extended to include palladium. Specifically, reductions of palladium salts by NaBH4 ... -
Structure and reactivity studies of simple phospholes
(1977)Newer techniques of phosphole synthesis, particularly those which lead to simple phospholes substituted with active functional groups, are briefly surveyed. A detailed account of chemical, physico-chemical, spectroscopic ... -
Studies in Group VIII metal-phosphine-tetrahydroborate chemistry
(1976)Co(I) and nickel(T) complexes containing both bidentate and monodentate tetrahydroborate have been prepared from the reductions of divalent metal compounds in the presence of triphenylphosphine with ethanolic sodium ... -
Studies in the coordination chemistry of phospholes
(1977)The chemical, physicochemical, theoretical and metal coordination studies of phospholes which have so far appeared in the literature are reviewed briefly with particular reference to the electronic structure of the ... -
Studies of the catalytic activities and resistance to sulphur poisoning of P-3 nickel and P-3 cobalt borides
(1976)The heterogeneous liquid-phase catalytic hydrogenation of alkenes over partially hydrogenated P-3 nickel and P-3 cobalt borides has been investigated. -
Synthetic approaches to five-membered heterocycles containing both ring and side-chain phosphorus atoms
(1983)A brief review of the importance and variety of symmetrical and unsymmetrical bisphosphines is given and the possible theoretical and synthetic value of bisphosphines in which one of the phosphorus atoms is included in ...