Reactions of Co(II) with sodium cyanotrihydroborate in the presence of a series of bidentate and some monodentate phosphines

dc.contributor.advisor	Holah, D. G.
dc.contributor.advisor	Hughes, A. N.
dc.contributor.author	Khan, Saeed Iftikhar
dc.date.accessioned	2017-06-06T13:40:32Z
dc.date.available	2017-06-06T13:40:32Z
dc.date.created	1981
dc.date.issued	1981
dc.identifier.uri	http://knowledgecommons.lakeheadu.ca/handle/2453/2380
dc.description.abstract	The reactions between Co(C10[subscript4])[subscript2].6H[subscript2]O or CoCl[subscript2].6H[subscript2]O, NaBH[subscript3]CN and some monodentate (PPh[subscript3] and Pcy[subscript3]) and a series of bidentate phosphines of the type Ph[subscript2]P-(CH[subscript2])[subscriptn]-PPh[subscript2] (n = 1-4) and also cis and trans Ph[subscript2]P-(CH[subscript2])[subscriptn]-PPh[subscript2] have been studied under a very wide range of experimental conditions. The reactions are affected by (1) the amount of NaBH[subscript3]CN used, (2) the rate of addition of NaBH[subscript3]CN, (3) the temperature, (4) the solvent used and (5) the reaction time. A number of cyanotrihydroborato and other complexes have been produced and others observed but not yet isolated.
dc.language.iso	en_US
dc.subject	Cobalt Isotopes
dc.subject	Sodium cyanotrihydroborate
dc.subject	Phosphenes
dc.title	Reactions of Co(II) with sodium cyanotrihydroborate in the presence of a series of bidentate and some monodentate phosphines
dc.type	Thesis
etd.degree.name	Master of Science
etd.degree.level	Master
etd.degree.discipline	Chemistry
etd.degree.grantor	Lakehead University