Complexes of ethylxanthate and N, N-diethyldithiocarbamate and their adducts with some nitrogen bases
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Authors
Murphy, Charles N.
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Abstract
This thesis concerns first row transition
metal complexes of ethylxanthate and diethyldithiocarbamate
(dtc). Complexes of the type
M(Xan)2 and (see document for formula) have been prepared and studied. It was found
that Cr(II) and Go{Il) could not be stabilized in
the presence of ethylxanthate, due to their tendency
to oxidize while Cu(II) was instantaneously reduced.
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Keywords
Diethyldithiocarbamate, Ethylxanthate, Metal oxidation states, Basic adducts of dithiolate complexes, Infra-red spectra